Perhaps the best-known ring-expansion reaction is the Baeyer-Villiger oxidation, first reported in 1899- not surprisingly by Adolf von Bayer and Victor Villiger. As we’re all aware, reaction of a carbonyl with a peracid generates a Criegee-type intermediate that undergoes rate-limiting concerted rearrangement to form an ester or lactone. The migration order is substituent dependant, with
Tag: Named chemical reactions
**Spoiler Alert** Below are the answers and references for our 2019 Named Chemical Reaction Quiz. If you want to try the quiz before looking at the answers click Here…
The delegates at our 6th Winter Process Chemistry Conference in Birmingham, UK had a little homework to do. See how you get on with our 2019 Named Chemical Reactions Quiz. Answers and references will be posted in the new year